70% Drop in Levels of Forever Chemicals Observed in Seabird Eggs Tracks Regulatory Success

Northern gannets on Bonaventure Island – credit, CC 3.0. BY-SA Bodoklecksel

Content of several “forever chemicals” in seabird eggs were found to have sharply decreased over the last 55 years by a team of scientists.

While first rising exponentially from during the 1960s, the chemicals, classed as PFAS, peaked in the 1990s before decreasing in line with regulatory oversight by North American governments.

PFAS are a class of chemicals that form water, stain, and heat-resistant coatings in multiple products which substantially contaminate environments around the world, and are linked to multiple detrimental health outcomes.

A study published in the journal Applied Toxicology that looked at PFAS concentrations in the eggs of northern gannets on Bonaventure Island found that the content of some of the most commonly used PFAS has fallen 70% and sometimes more.

These include perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA), which fell 74% and 40% respectively. Concentrations of perfluorohexanesulfonic acid, (PFHxS) another of these chemicals, was also 70% lower from baseline.

“We see this incredible rise to a peak where concentrations seem to be higher than toxicological threshold for those birds, then it really decreases in a nice way,” Raphael Lavoie, a co-author and ecotoxicologist with Environment and Climate Change Canada, told the Guardian. “The regulations are having a good effect.”

The seabird subjects and the long study period were notable strengths. The 55 years of data spans the rise in PFAS production, and the eventual decline as the environmental groups and regulators caught on to the toxicity in the late 90s and early 2000s.

Bonaventure Island is the world’s largest northern gannet breeding colony. These pescatarian birds are directly exposed to PFAS contamination due to the island’s position near the St. Lawrence Seaway, which, being connected to the Great Lakes manufacturing centers north and south of the border, was exposed to substantial amounts of PFAS during the 20th century.

The PFAS got into the fish which got into the gannets and then into their eggs. Tom Perkins for the Guardian wrote that in the late 90s, the chemical corporation M3 dramatically scaled back its production of commercial PFAS in the face of regulatory scrutiny. In 2015, the chemical sector struck an agreement with the EPA to phase out production of PFOA and PFOS, while 6 years earlier at the United Nations’ Stockholm Convention, several of the chemicals tested for in the study were subjected to elimination.

This included PFOA and PFHxS, while PFOS was restricted in everything but firefighting foam.

The study is a comprehensive demonstration of how these regulations are working to reduce the toxic load presented by PFAS in the environment. PFAS are referred to shorthanded as “forever chemicals,” however, and so the authors stress the need for continual environmental and regulatory vigilance, since any similar chemicals entering the environment today will remain, presumably forever. 70% Drop in Levels of Forever Chemicals Observed in Seabird Eggs Tracks Regulatory Success
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Multiple Types of Plastic Are Turned into Vinegar Using Sunlight-Powered Process Without Emissions

Waterloo PhD student Wei Wei, who led the research – credit, University of Waterloo, released

Researchers at the University of Waterloo have discovered a way to turn plastic waste into acetic acid, the main ingredient of vinegar, using sunlight.

The breakthrough offers a promising new approach to reducing plastic pollution through photocatalysis, while simultaneously creating a useful, value-added chemical product through a process inspired by nature.

“Our goal was to solve the plastic pollution challenge by converting microplastic waste into high-value products using sunlight,” said Dr. Yimin Wu, a professor of mechanical and mechatronics engineering at the University of Waterloo, Canada.

Plastic waste, notably microplastics, has been found across many of the planet’s ecosystems, raising concerns about threats to terrestrial and marine life as well as human health. Plastic recycling rates remain low around the globe.

To tackle this problem, the team developed a bio-inspired photocatalysis process using iron atoms embedded in carbon nitride, a way that certain types of fungi break down organic matter using enzymes.

When exposed to sunlight, the material drives a series of chemical reactions that transform plastic polymers into acetic acid with high selectivity. The reaction takes place in water, making it particularly relevant for addressing plastic pollution in aquatic environments.

Acetic acid is widely used in food production, chemical manufacturing and energy applications. The study shows it can be produced from common plastic wastes, including PVC, PP, PE and PET, and remains effective across mixed plastic compositions.

This makes the approach well suited to real-world waste streams, offering a promising alternative to plastic incineration, and could support more circular approaches to material use while providing a new strategy for upcycling plastics.

“Both from a business and societal perspective, the financial and economic benefits associated with this innovation seem promising,” said Roy Brouwer, executive director of the Water Institute and a coauthor of the article supporting the techno-economic analysis.

“This method allows abundant and free solar energy to break down plastic pollution without adding extra carbon dioxide to the atmosphere,” Wu adds.

The findings also point to new possibilities for addressing microplastics directly. Because the process degrades plastics at the chemical level, it could help prevent the accumulation of microplastics in water systems.While still at the laboratory stage, the team envisions that this approach could be adapted for scalable, solar-driven recycling and environmental cleanup and the photocatalytic upcycling system can be further enhanced through strategic engineering of the materials and manufacturing processes. Multiple Types of Plastic Are Turned into Vinegar Using Sunlight-Powered Process Without Emissions
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